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논문 기본 정보
- 자료유형
- 학술대회자료
- 저자정보
- 발행연도
- 2021.5
- 수록면
- 74 - 74 (1page)
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Electrochemical sensors and biosensors based on electrochemiluminescence (ECL) of luminol and tris(2,2’-bipyridyl) ruthenium(II) (Ru(bpy)<sub>3</sub><sup>2+</sup>) haven developed over the last 20 years in my laboratory. ECL has attracted much attention as a powerful analytical tool due to its inherent sensitivity, selectivity, and wide linear dynamic range for a variety of analytes such as alkylamines, amino acids, NADH, and a number of pharmaceutical compounds. The ECL emission of the Ru(bpy)<sub>3</sub><sup>2+</sup>/analyte system presumably arises from the energetic electron transfer between the electrogenerated Ru(bpy)<sub>3</sub><sup>3+</sup> and a strong reducing intermediate (reductant) formed by the oxidation of analytes. The reaction scheme for Ru(bpy)<sub>3</sub><sup>2+</sup> ECL indicates that the starting material Ru(bpy)<sub>3</sub><sup>2+</sup> is regenerated in-si^_@span style=color:#999999 ^_# ... ^_@/span^_#^_@a href=javascript:; onclick=onClickReadNode('NODE10557953');fn_statistics('Z354','null','null'); style='color:#999999;font-size:14px;text-decoration:underline;' ^_#전체 초록 보기^_@/a^_#
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