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논문 기본 정보

자료유형
학위논문
저자정보

염효열 (수원대학교, 수원대학교 대학원)

지도교수
이성재
발행연도
2015
저작권
수원대학교 논문은 저작권에 의해 보호받습니다.

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이 논문의 연구 히스토리 (2)

초록· 키워드

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Carbon-based nanofillers such as graphene, carbon nanotube, carbon black and nanoscale graphite are frequently used to enhance the performance for polymer nanocomposites. In this study, polystyrene (PS) and carbon-based nanofiller nanocomposites were prepared via latex technology and investigated to compare the effect of nanofiller types on rheological and electrical properties of the nanocomposites. Graphene oxide (GO) sheets, poly(styrene sulfonate)-coated reduced graphene oxide (PSS-RGO) sheets, carbon nanotubes (CNTs) and graphite nanoplatelets (GNPs) were used as model nanofillers, and their characteristics and the properties of nanocomposites were compared. GO sheets were synthesized by using the modified Hummers'' method from a commercial graphite, and PSS-RGO sheets were prepared by the reduction of GO-dispersed PSS solution with hydrazine monohydrate, whereas commercial grades were used for CNTs and GNPs without chemical treatments. Good dispersions in aqueous solution were achieved both for GO sheets and for PSS-RGO sheets, but CNTs and GNPs were able to be dispersed with the help of surfactant. GNPs were hardly dispersed because they exist in aggregate form of graphene layers. Rheological properties of PS/GO, PS/PSS-RGO and PS/CNT nanocomposites were highly increased with the inclusion of nanofillers, resulting in rheological percolation thresholds less than 1 wt% Electrically conducting pathways of PS/GO, PS/PSS-RGO, PS/CNT and PS/GNP nanocomposites were achieved at the electrical percolation threshold of 0.50, 1.01, 0.25 and 5.82 wt% of nanofillers, respectively. Among the nanofillers used in this study, PS/CNT nanocomposites showed the highest electrical conductivity and the lowest electrical percolation threshold, and on the contrary the increase of electrical conductivity of PS/GNP nanocomposites was the smallest. Both PS/GO and PS/PSS-RGO nanocomposites showed well dispersed morphology, but the electrical conductivity was better in PS/GO nanocomposites. It is speculated that the electrical conductivity PS/GO nanocomposites was further increased by the thermal reduction of GO sheets during molding. On the contrary, the PS/PSS-RGO nanocomposites showed lower electrical conductivity because the RGO portion is only half in PSS-RGO content and RGO sheets were blocked by the same amount of non-conducting PSS chains.

목차

Ⅰ. 서론 1
1. 연구배경 1
2. 탄소기반 나노필러 4
1) 그래핀 4
2) 탄소나노튜브 8
3) 나노흑연 10
Ⅱ. 실험 11
1. 시약 및 재료 11
2. 단분산 PS 입자 합성 12
3. 나노필러 합성 13
4. PS/나노필러 나노복합재료의 제조 15
1) PS/CNT 및 PS/GNP 나노복합재료 제조 15
2) PS/GO 및 PS/PSS-RGO 나노복합재료 제조 15
5. 분석 17
1) 나노필러 분석 17
2) 모폴로지 분석 17
3) 유변물성 측정 17
4) 전기전도도 측정 18
Ⅲ. 결과 및 고찰 19
1. 나노필러 분석 19
1) XRD 분석 19
2) TGA 분석 21
3) FT-IR 분석 23
4) XPS 분석 25
5) 온도에 따른 GO의 전기 전도성 27
2. 무유화제 유화 중합에 의해 제조된 PS 입자 29
3. 나노필러의 종류에 따른 나노복합재료의 물성 32
1) 나노필러 종류에 따른 모폴로지 32
2) 나노필러 종류에 따른 유변물성 36
3) 나노필러 종류에 따른 전기 전도도 44
Ⅳ. 결론 48
Ⅴ. 참고 문헌 51

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