메뉴 건너뛰기
.. 내서재 .. 알림
소속 기관/학교 인증
인증하면 논문, 학술자료 등을  무료로 열람할 수 있어요.
한국대학교, 누리자동차, 시립도서관 등 나의 기관을 확인해보세요
(국내 대학 90% 이상 구독 중)
로그인 회원가입 고객센터 ENG
주제분류

추천
검색

논문 기본 정보

자료유형
학위논문
저자정보

전유상 (고려대학교, 고려대학교 대학원)

지도교수
김영근
발행연도
2020
저작권
고려대학교 논문은 저작권에 의해 보호받습니다.

이용수0

표지
AI에게 요청하기
추천
검색

이 논문의 연구 히스토리 (2)

초록· 키워드

오류제보하기
1-dimensional nanomaterials which have the merits of large shape anisotropy and facile surface modification via binding of various chemicals and biological molecules, have drawn attention for their potential applications in biomedical sensors, energy storage, and magnetics. Among them, tubular and helical structures have recently received lots of attention due to their unique effects on the structural features instead of cylindrical shapes. For examples, nanotubes have an advantage over nanowires because of their larger specific surface areas including interior and exterior ones. On the other hands, helical nanosprings are promising among different systems, because of their additional advantage their motion can be controlled by magnetic field. As an example of application, under an external field, the helical NSs can be used as sensors, rotors and actuators. Furthermore, both of them have shown unique magnetic properties driven by their special shapes which are expected to create emerging concept of nanodevices such as nanorobots, nanomagnets, nanosensors, and magnetic memory. While the basic scientific knowledge and performance of applications have been greatly improved, there has been challenging to fabricate cheap, uniform and various materials of tubular and helical structures. In this dissertation, I introduce a facile synthesis method for modulating the morphology of Co based nanotubes and nanosprings prepared by template assisted electrodeposition without complication of conventional system for manufacturing nanowires. Co based nanotubes and nanosprings are synthesized by adding an additive with a concentration ratio of vanadyl ions (VO2+) divided by ascorbic acid to the existing metal precursor solution. Furthermore, I scrutinize the crystallization pathway of each shape in the spatially confined environment such as anodized aluminum oxide. To understand the formation mechanism, I confirm the chemical atmosphere and electronic flow on the surface of dielectric materials. Moreover, I utilize the non-classical crystallization models to explain their microstructural changes according to the various synthesis conditions.

목차

Chapter 1. Introduction
1.1. Overview 1
1.2. Outline of the dissertation 5
Chapter 2. Theoretical background
2.1. Template-assisted electrochemical deposition 6
2.2. Electrolytes 17
2.3. Electrical flow models in micro/nanochannels 34
Chapter 3. Tubular structures via the incorporation of vanadyl ions
3.1. Introduction 38
3.2. Materials and methods 40
3.3. Results and discussion 42
3.4. Conclusion 57
Chapter 4. Crystallization process of helical structures
4.1. Introduction 58
4.2. Materials and Methods 60
4.3. Results and Discussion 62
4.4. Conclusion 93
References 95
Acknowledgements 108

최근 본 자료

전체보기

댓글(0)

0